Open AccessEco-friendly, renewable Crambe abyssinica Hochst-based adsorbents remove high quantities of Zn2+ in water
Author(s) -
Daniel Schwantes,
Affonso Celso Gonçalves,
Andréia da Paz Schiller,
Luiz Alberto Verderio Bianco,
Andressa Giombelli Rosenberger
Publication year - 2020
Publication title -
journal of environmental health science and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.447
H-Index - 45
ISSN - 2052-336X
DOI - 10.1007/s40201-020-00505-9
Subject(s) - crambe , adsorption , freundlich equation , chemistry , langmuir , sorbent , carbonization , chemical engineering , nuclear chemistry , organic chemistry , botany , engineering , biology
Although not considered poisonous and with natural occurrence, Zn contamination is mainly related to anthropic actions. This research aim was to develop, from crambe wastes, adsorbents with high adsorption capacity of Zn 2+ . The crambe biomass was modified with H 2 O 2 , H 2 SO 4 and NaOH 0.1 mol L -1 , resulting in four crambe-based adsorbents: C. in natura (unmodified), C. H 2 O 2 , C. H 2 SO 4 and C. NaOH. These were studied by determination of their chemical components, SEM, FTIR, pH PZC , thermal stability (by TG/DTG curves), SSA, pore volume and pore diameter (by BET and BJH). Adsorption studies were also carried out to evaluate its Zn removal capacity. Evaluations were taken on adsorbent dose and the influence of the pH, as well as studies on adsorption kinetics and equilibrium. These results were evaluated by pseudo-first order, pseudo-second order, Elovich, intraparticle diffusion, Langmuir, Freundlich, Dubinin-Radushkevich and Sips (linear and nonlinear models). Results show that the crambe-based adsorbents may have functional groups such as hydroxyls, amides, carbonyls and carboxylates, which may be responsible for the Zn 2+ adsorption. The materials have heterogeneous structure, allowing the occurrence of mono and multilayer adsorption of Zn. The finest results point out the occurrence of mono and multilayer of Zn 2+ (evidenced by Sips-nonlinear model), with an increase in Q sat of 72% (C. H 2 O 2 ), 22% (C. H 2 SO 4 ) and 80% (C. NaOH). The developed crambe adsorbents have low cost of production (since the raw material is until now a solid waste) and have high removal ratio of Zn 2+ from waters, being a promising technology.