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Pseudohalogenation of methyl 9‐hydroxy‐ cis ‐12‐and 12‐hydroxy‐ cis ‐9‐octadecenoate
Author(s) -
Naqvi Fehmida,
Rauf Abdul,
Siddiqui M. M.,
Ahmad M. S.,
Osman S. M.
Publication year - 1997
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/s11746-997-0206-x
Subject(s) - chemistry , elemental analysis , spectral analysis , stereochemistry , medicinal chemistry , organic chemistry , spectroscopy , physics , quantum mechanics
Pseudohalogenation of methyl 9‐hydroxy‐ cis ‐12‐octadecenoate ( I ) and methyl 12‐hydroxy‐ cis ‐9‐octadecenoate ( II ) has been carried out with N,N ‐dibromobenzenesulfonamide (NNDBS). Compounds I and II , on reaction with NNDBS, formed four and three products, respectively. The interesting feature of these reactions was the formation of 1,4‐epoxy compounds. The structures of individual compounds were established with the help of elemental and spectral analysis.