Kinetics of epoxidation of alkyl esters of undecylenic acid: Comparison of traditional routes vs. ishii‐venturello chemistry | Zendy

Yadav G. D. | Zendy; Satoskar D. V. | Zendy

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Kinetics of epoxidation of alkyl esters of undecylenic acid: Comparison of traditional routes vs. ishii‐venturello chemistry

Author(s) -

Yadav G. D.,

Satoskar D. V.

Publication year - 1997

Publication title -

journal of the american oil chemists' society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.512

H-Index - 117

eISSN - 1558-9331

pISSN - 0003-021X

DOI - 10.1007/s11746-997-0097-x

Subject(s) - chemistry , kinetics , alkyl , catalysis , aqueous solution , organic chemistry , aqueous two phase system , physics , quantum mechanics

Epoxidation of undecylenic acid and its methyl and ethyl esters with aqueous H 2 O 2 was carried out by using different traditional routes, ion exchange resin, and the newly developed synergistic usage of heteropoly acids and phase transfer catalysis in a biphasic system. The so‐called Ishii‐Venturello chemistry was employed to develop a kinetic model. Interesting selectivities are obtained.

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