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Synthetic Base Stock Based on Guerbet Alcohols
Author(s) -
Waykole Chetan,
Bhowmick DiptiNarayan,
Pratap Amit
Publication year - 2014
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/s11746-014-2484-4
Subject(s) - viscosity index , pour point , flash point , branching (polymer chemistry) , organic chemistry , base oil , fatty alcohol , chemistry , catalysis , carbon fibers , base (topology) , viscosity , toluene , materials science , chemical engineering , composite material , scanning electron microscope , mathematical analysis , mathematics , composite number , engineering
Guerbet (β branched) alcohols of varying chain length of even carbon numbers were synthesized by using single linear fatty alcohols ranging from 1‐octanol to 1‐dodecanol. All Guerbet alcohols having fewer than 28 carbon atoms and are liquid at 0 °C due to β branching. Synthetic base oils were prepared by reacting commonly available unsaturated fatty acids and dicarboxylic acids with Guerbet alcohols using p ‐toluenesulfonic acid as a catalyst. These base oils were characterized by physical and tribological properties like viscosity, viscosity index, pour point, flash point, wear scar, weld load, coefficient of friction etc. and compared with commercially available 150 and 500 N base oils.