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Experimental Solid–Liquid Phase Equilibria of a Methyl Ester/Amide/Nitrile Ternary System by DSC
Author(s) -
MekkiBerrada A.,
Bennici S.,
Dubois J.L.,
Auroux A.
Publication year - 2013
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/s11746-013-2320-2
Subject(s) - differential scanning calorimetry , ternary operation , nitrile , eutectic system , ternary numeral system , amide , phase (matter) , materials science , binary system , chemistry , organic chemistry , thermodynamics , binary number , alloy , physics , arithmetic , mathematics , computer science , programming language
Binary and ternary mixtures of lauric methyl ester, amide and nitrile were investigated by differential scanning calorimetry, in order to determine the solid–liquid phase equilibria of this model for saturated organic systems. Eutectic mixtures were observed and followed in the ternary system, while solid–solid transitions and immiscibility phenomena were also characterized. This system is also of industrial interest for processes in the frame of biomass valorization.