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Correlation of Rheological and Microstructural Properties in a Model Lipid System
Author(s) -
Liang Baomin,
Shi Yuping,
Hartel Richard W.
Publication year - 2008
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/s11746-008-1213-2
Subject(s) - microstructure , materials science , rheology , fractal dimension , dynamic mechanical analysis , composite material , crystallization , texture (cosmology) , modulus , fractal , thermodynamics , mathematics , mathematical analysis , physics , image (mathematics) , artificial intelligence , computer science , polymer
Model systems having different microstructures and rheological properties were obtained by controlled crystallization from a mixture of high‐melting and low‐melting lipids. Based on analysis of confocal scanning light microscopic images, the microstructural characteristics of the systems were quantified by use of different approaches including microstructure density, Euler characteristic, nearest‐neighbor analysis, fractal dimension of microstructure interface, and fractal dimension by the particle‐counting method (PCM). The solid‐fat content (SFC) of semisolid lipid samples was measured by nuclear magnetic resonance (NMR) spectroscopy and rheological properties were analyzed by compressive penetration tests with a texture analyzer. As expected, SFC had a major impact on rheological properties, but lipid crystalline microstructure also had significant effects. Correlation analysis showed that rheological properties were highly correlated with the various quantitative microstructural parameters, with the exception of the fractal dimension by the PCM. Empirical models adequately correlated rheological properties with SFC and microstructure density. Compression modulus increased by a factor of about ten as SFC increased from 0.28 to 0.51. However, for systems with the same SFC, compression modulus was dependent on microstructure. At low SFC compression modulus increased by about a factor of seven over the range of microstructures formed, whereas at higher SFC compression modulus only increased by a factor of about two.