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A potential biodegradable rubber—Viscoelastic properties of a soybean oil‐based composite
Author(s) -
Xu Jingyuan,
Liu Zengshe,
Erhan Sevim Z.,
Carriere Craig J.
Publication year - 2002
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/s11746-002-0528-0
Subject(s) - viscoelasticity , materials science , rheology , composite material , natural rubber , stress relaxation , biomaterial , biopolymer , dynamic mechanical analysis , soybean oil , epoxidized soybean oil , dynamic modulus , composite number , modulus , elasticity (physics) , polymer , creep , chemistry , organic chemistry , nanotechnology , food science , raw material
Scientists are more and more interested in biodegradable materials owing to their environmental advantage. We investigated viscoelastic properties of a newly developed biomaterial made from epoxidized soybean oil (ESO). ESO cross‐linked by triethylene glycol diamine exhibited viscoelastic solid properties. The storage modulus ( G ′) was 2×10 4 Pa over four frequency decades. The phase angles were 14–18°. Stress relaxation measurements showed that there was no relaxation up to 500 s. From the plateau modulus we estimated that the M.W. of this cross‐linked soybean oil was on the order of 10 5 . The composites of cross‐linked ESO with three different fibers had 50 times higher elasticity ( G ′) than those without fiber. Phase shifts were the same as those of cross‐linked oil without fibers, but the linear range of rheological properties was much narrower than that of the material without fibers. All these results indicated that this new biopolymer made from soybean oil exhibited strong viscoelastic solid properties similar to synthetic rubbers. These rheological properties implied that this biomaterial has high potential to replace some of the synthetic rubber and/or plastics.