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Preparation of monodispersed emulsion with large droplets using microchannel emulsification
Author(s) -
Sugiura Shinji,
Nakajima Mitsutoshi,
Seki Minoru
Publication year - 2002
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/s11746-002-0517-6
Subject(s) - microchannel , emulsion , materials science , terrace (agriculture) , surface tension , membrane emulsification , analytical chemistry (journal) , composite material , nanotechnology , chemistry , chromatography , thermodynamics , physics , archaeology , history , biochemistry
Microchannel (MC) emulsification is a novel technique for producing monodispersed emulsions with coefficients of variation of less than 5%. To produce emulsions with large droplets, we designed three MC with large dimensions. The MC structure consists of two parts: a channel and a terrace. Terrace length was defined as the length from the exit of the MC to the end of the terrace. The MC plates used in this study have deeper channels and longer terraces. The size limit of droplets prepared by MC emulsification was studied. Monodispersed emulsions with droplets as large as 100 μm were prepared using an MC with a depth of 16 μm and a terrace length of 240 μm. The average diameter (coefficient of variation) of the emulsion droplets was 98.1 μm (2.5%). Emulsions with larger‐diameter droplets were prepared using an MC with a longer terrace. The effect of the applied pressure on emulsification behavior was studied and discussed from the viewpoint of the droplet formation mechanism. At low applied pressures, droplet diameters were independent of the applied pressure, and monodispersed emulsions were produced. The pressure ranges of constant droplet diameter for large‐droplet emulsions were narrower than those for the 5 to 30 μm droplet size emulsions because interfacial tension is more significant on a smaller scale compared with the other forces.