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Fullerene lipids: Synthesis of dialkyl 1,2‐[6,6]‐methano‐[60]‐fullerene dicarboxylate derivatives
Author(s) -
Lie Ken Jie Marcel S. F.,
Cheung Sunny WaiHung
Publication year - 1998
Publication title -
lipids
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.601
H-Index - 120
eISSN - 1558-9307
pISSN - 0024-4201
DOI - 10.1007/s11745-998-0263-1
Subject(s) - fullerene , chemistry , adduct , alkyl , fullerene chemistry , sodium hydride , hydride , organic chemistry , medicinal chemistry , hydrogen
Reaction of C 60 fullerene with dialkyl bromomalonate (where the alkyl groups consist of short‐, medium‐, and long‐saturated chains or unsaturated long chains) in the presence of sodium hydride gives [6,6]‐bridged mono‐adducts of methanofullerene. The spectroscopic properties of such fullerenoid lipids are reported.