New glycosphingolipid containing an unusual sphingoid base from the basidiomycete  Polyporus ellisii | Zendy

Gao JinMing | Zendy; Hu Lin | Zendy; Dong ZeJun | Zendy; Liu JiKai | Zendy

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New glycosphingolipid containing an unusual sphingoid base from the basidiomycete Polyporus ellisii

Author(s) -

Gao JinMing,

Hu Lin,

Dong ZeJun,

Liu JiKai

Publication year - 2001

Publication title -

lipids

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.601

H-Index - 120

eISSN - 1558-9307

pISSN - 0024-4201

DOI - 10.1007/s11745-001-0752-2

Subject(s) - glycosphingolipid , polyporus , chemistry , glucocerebroside , chloroform , cerebroside , stereochemistry , methanol , mass spectrometry , organic chemistry , chromatography , biochemistry , glucocerebrosidase , enzyme

A new 9‐methyl‐sphinga‐4,8‐dienine‐containing glucocerebroside ( 1 ), together with two additional known analogs, cerebrosides B and D, was isolated from the chloroform‐soluble lipid fraction of the ethanol and chloroform/methanol extract of the fruiting bodies of the basidiomycete Polyporus ellisli Berk. and characterized. The structure and relative stereochemistry of the new compound were identified as (2 S ,3 R ,4 E ,8 E )‐1‐(β‐ d ‐glucopyranosyl)‐3‐hydroxy‐2‐[( R )‐2′‐hydroxyheptadecanoyl]amino‐9‐methyl‐4,8‐octadecadiene by means of spectroscopic ( 1 H, 13 C, and two‐dimensional nuclear magnetic resonance; mass spectrometry) and chemical methods.

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