Simultaneous derivatization of acyl and  S ‐alkyl moieties of acyl thioesters by using trimethylsulfonium hydroxide for gas chromatographic analysis | Zendy

Klein Erika | Zendy; Weber Nikolaus | Zendy

Premium

Simultaneous derivatization of acyl and S ‐alkyl moieties of acyl thioesters by using trimethylsulfonium hydroxide for gas chromatographic analysis

Author(s) -

Klein Erika,

Weber Nikolaus

Publication year - 2000

Publication title -

lipids

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.601

H-Index - 120

eISSN - 1558-9307

pISSN - 0024-4201

DOI - 10.1007/s11745-000-558-2

Subject(s) - derivatization , chemistry , thioester , lauric acid , chromatography , alkyl , organic chemistry , gas chromatography , methanol , acyl group , fatty acid , high performance liquid chromatography , enzyme

The reaction of long‐chain acyl thioesters, viz . lauric acid dodecyl thioester, 1,8‐di‐ S ‐palmitoyl octanedithiol, and tristearoyl α‐monothioglycerol, with trimethylsulfonium hydroxide in the presence of methanol leads to simultaneous derivatization of acyl moieties and S ‐alkyl moieties of acyl thioesters to the corresponding fatty acid methyl esters and methyl alkylsulfides, respectively. These derivatized products were analyzed by gas chromatographic technique.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research