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Interaction of Cetrimide with Nonionic Surfactants—Triton X‐100 and Brij‐35: A Conductometric and Tensiometric Study
Author(s) -
Ali Anwar,
Malik Nisar Ahmad,
Farooq Ummer,
Tasneem Shadma,
Nabi Firdosa
Publication year - 2016
Publication title -
journal of surfactants and detergents
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.349
H-Index - 48
eISSN - 1558-9293
pISSN - 1097-3958
DOI - 10.1007/s11743-016-1800-4
Subject(s) - chemistry , pulmonary surfactant , gibbs free energy , cetrimide , surface tension , micelle , mole fraction , critical micelle concentration , gibbs isotherm , nonionic surfactant , thermodynamics , thermodynamics of micellization , bromide , analytical chemistry (journal) , chromatography , organic chemistry , aqueous solution , medicine , biochemistry , physics , dentistry , chlorhexidine
Conductometric and surface tension techniques were employed to study the different mole fractions of nonionic surfactants (TX‐100 and Brij‐35) with cetrimide. The standard Gibbs energies of micellization ( Δ G m 0 ) and the Gibbs energies of transfer ( Δ G trans 0 ) in the mixture of surfactants were also calculated; the micellization becomes more spontaneous on increasing the amount of nonionic surfactants in the mixture. It was observed that the values of excess surface concentration (Γ max ) in surfactant mixtures decrease in comparison to the pure surfactants but the values of minimum area per surfactant molecule ( A min ) increase in surfactant mixtures than in the pure ones. It was also observed that the values of the interaction parameter ( β ) are negative at all mole fractions. A gradual decrease in β with temperature is observed indicating the synergism between the two components and is attributed to the decrease in the electrostatic repulsion between the charged heads of the cationic surfactant as the nonionic surfactant is being intercalated into the micelle. The activity coefficients were found out to be less than unity confirming nonideality of the system and the negative values of excess free energy of mixing confirm that the mixed micelles formed were stable.