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Dissolution of Soap Scum by Surfactant. Part II: Effects of NaCl and Added Chelant on Equilibrium Solubility and Dissolution Rate of Calcium Soap Scum in Amphoteric Surfactant Solutions
Author(s) -
Itsadat Sawwalak,
Ratanalert Darunrat,
Soontravanich Sukhwan,
Scamehorn John F.,
Sabatini David A.,
Chavadej Sumaeth
Publication year - 2014
Publication title -
journal of surfactants and detergents
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.349
H-Index - 48
eISSN - 1558-9293
pISSN - 1097-3958
DOI - 10.1007/s11743-014-1583-4
Subject(s) - chemistry , dissolution , solubility , pulmonary surfactant , solubility equilibrium , inorganic chemistry , aqueous solution , salt (chemistry) , organic chemistry , biochemistry
The effects of solution pH and NaCl on the equilibrium solubility and dissolution rate of a model soap scum (calcium octadecanoate or calcium stearate) in aqueous solutions of dimethyldodecylamine oxide surfactant (DDAO) with and without chelant disodium ethylenediaminetetraacetate are reported. The equilibrium solubility and dissolution rate of soap scum increased with increasing solution pH when the chelant was added in the DDAO system while in the chelant‐free systems the opposite trend was observed. The added NaCl has an ambiguous effect on the solubility and dissolution rate of soap scum in the absence of chelant, but a small level of added NaCl reduces both solubility and the dissolution rate constant in the presence of chelant. Both equilibrium and kinetics of dissolution are maximized at high pH with DDAO/chelant and no added salt.