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Enolate anions from lipid derivatives. Alkylation of acylisopropylidene glycerols
Author(s) -
Herslöf M.,
Gronowitz S.
Publication year - 1985
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02935704
Subject(s) - alkylation , glycerol , chemistry , alkyl , organic chemistry , medicinal chemistry , catalysis
The enolate anions from isopropylidene protected monoacylglycerols have been successfully alkylated with alkyl iodides of various chain length. From these products the corresponding monoacylglycerols and triacylglycerols can be prepared. This is exemplified by the synthesis of 2‐butyldodecanoyl‐didodecanoyl glycerol, di‐2‐butyldodecanoyl‐dodecanoyl glycerol and tri‐2‐butyldodecanoyl glycerol.