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Methanesulfonic acid‐catalyzed additions IV. Additions to methyl linoleate
Author(s) -
Eisner Abner,
Perlstein Theodore,
Ault W. C.
Publication year - 1964
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02898135
Subject(s) - methanesulfonic acid , chemistry , phenol , catalysis , anisole , resorcinol , adduct , oleic acid , organic chemistry , solvent , ether , phenols , medicinal chemistry , biochemistry
Varied aromatic compounds including phenol, o ‐chlorophenol, 2‐naphthol, resorcinol, methyl salicylate, anisole, phenetole, p ‐toluenethiol, p ‐chlorobenzenethiol and 2‐napthalenethiol were added to methyl linoleate. Using methanesulfonic acid as a solvent‐catalyst the additions took place as readily as to oleic acid in previous experiments. The recovery of mono‐adducts, however, was complicated by the presence of di‐adducts and presumably polymeric material. As observed in the earlier oleic acid studies, evidence for the formation of ether intermediates was obtained. The only identified products from arylthiol additions were thioethers.