Positron annihilation studies on nasicon analogues containing cation vacancies
Author(s) -
V. Sreeramalu,
H. R. Sreepad,
A. Chandrashekara,
V. Ravindrachary,
S. Gopal
Publication year - 1990
Publication title -
bulletin of materials science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.35
H-Index - 72
eISSN - 0973-7669
pISSN - 0250-4707
DOI - 10.1007/bf02744948
Subject(s) - positron , materials science , annihilation , positron annihilation , trapping , atomic physics , fast ion conductor , nuclear physics , chemistry , physics , electron , electrode , ecology , biology , electrolyte
Positron annihilation studies were carried out on the Nasicon analogue Na2(La, Al)Zr(PO4)3 compound for three different concentrations (2·2, 2·8 and 5·2 by wt.%) of ZrO2 in the nutrient. Angular correlation study of annihilated photons reveals that the defect concentration is maximum for 2·8 (wt.%) of ZrO2. Further, positron lifetime studies indicate that the positrons are trapped at cation vacancies. Application of a two-state trapping model to this system made it possible to evaluate the lifetime of positrons in the Bloch state and of positrons trapped at cation vacancies
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