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Vapor‐Phase hydrogenation of methyl linoleate in the presence of a supported copper catalyst
Author(s) -
Lidefelt J. O.,
Magnusson J.,
Schöön N. H.
Publication year - 1983
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02679795
Subject(s) - catalysis , copper , vapor phase , kinetics , adsorption , hydrogen , chemistry , phase (matter) , gas phase , absorption (acoustics) , reaction mechanism , inorganic chemistry , organic chemistry , materials science , thermodynamics , composite material , physics , quantum mechanics
Methyl linoleate was hydrogenated in the vapor phase in the presence of a copper‐on‐alpha alumina catalyst. The kinetics of the reaction could be formulated with a Eley‐Rideal mechanism including the reaction between chemisorbed methyl ester and hydrogen in the gas phase. The absorption coefficients in the rate equation were based on separately performed adsorption studies recently reported.

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