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Studies on nitrosochlorination of olefinic fatty acids: I
Author(s) -
Hasan S. Q.,
Ahmad I.,
Ahmad Fashih,
Osman S. M.
Publication year - 1983
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02666578
Subject(s) - methyl oleate , chemistry , dimer , organic chemistry , medicinal chemistry , catalysis
Nitrosochlorination of methyl oleate yielded methyl 9(10)‐chloro‐10(9)‐nitrosooctadecanoate, methyl 9(10)‐chloro‐10(9)‐oximinooctadecanoate and an abnormal product 9(10)‐chloro‐10(9)‐nitriminooctadecanoate. A similar reaction with 10‐undecenoate yielded a dimer of methyl 10‐chloro‐11‐nitrosoundecanoate, methyl 10‐chloro‐11‐oximinoundecanoate and methyl‐10‐chloro‐11‐nitriminoundecanoate. On the other hand, methyl trans ‐2‐doxosenoate reacted reluctantly up to 10%, yielding methyl 2‐oximino‐3‐chlorodocosanoate. All these products have been characterized with the help of compositional and spectral data.