Preparation and etherification reaction of fatty dichlorocyclopropanes | Zendy

Kenney H. E. | Zendy; Komanowsky Daria | Zendy; Cook Linda L. | Zendy; Wrigley A. N. | Zendy

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Preparation and etherification reaction of fatty dichlorocyclopropanes

Author(s) -

Kenney H. E.,

Komanowsky Daria,

Cook Linda L.,

Wrigley A. N.

Publication year - 1964

Publication title -

journal of the american oil chemists' society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.512

H-Index - 117

eISSN - 1558-9331

pISSN - 0003-021X

DOI - 10.1007/bf02661913

Subject(s) - ether , chemistry , organic chemistry , dichlorocarbene , fatty acid methyl ester , ring (chemistry) , medicinal chemistry , catalysis , biodiesel

Dichlorocarbene was added to cis ‐9‐octadecene, methyl oleate, methyl elaidate, and methyl linoleate to form the corresponding mono‐ or bis‐dichlorocyclopropanes in yields of 75舑88%. The dichlorocyclopropanes underwent ring‐opening substitution on heating with alcohols (or water) to form ॆ‐chlorallylic ethers (or alcohols). The ethers were obtained in yields of 46 to 84%. Tetraethylene glycol and methyl lactate, as hydroxyl compounds, gave a polyethenoxy ester and an ether‐linked diester, respectively.

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