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Hydrozirconation of oleyl alcohol
Author(s) -
Karlsson Susanne,
Hallberg Anders,
Gronowitz Salo
Publication year - 1989
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02660755
Subject(s) - oleyl alcohol , alcohol , halogenation , zirconium , alkyl , chemistry , carbonylation , organic chemistry , medicinal chemistry , catalysis , carbon monoxide
Hydrozirconation of oleyl alcohol gave a mixture of the ω‐and γ‐zirconium‐stearyl alcohols. The zirconium alkyl bonds were cleaved by reaction with D 2 O, Br 2 or CO‐Br 2 ‐2‐methoxyethanol. 18‐Bromo‐stearyl alcohol (X) and 3‐bromo‐stearyl alcohol (IX) were isolated after bromination and 2‐methoxyethyl 19‐hydroxynonadecanoate (XII) and dihydro‐3‐pentadecyl‐2(3H)‐furanone (XIII) after carbonylation.