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Hydroxy unsaturated oils. II. Preparation and characterization of methyl dimorphecolate and methyl lesquerolate from Dimorphotheca and Lesquerella oils
Author(s) -
Diamond M. J.,
Knowles R. E.,
Binder R. G.,
Goldblatt L. A.
Publication year - 1964
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02654876
Subject(s) - anhydrous , chemistry , acetonitrile , distillation , chromatography , pentane , organic chemistry , methyl oleate , glyceride , catalysis , crystallization , sodium methoxide , fatty acid
An evaluation was made of several procedures for the preparation and purification of methyl dimorphecolate and methyl lesquerolate. An anhydrous anion exchange resin in the methoxide form was a catalyst for the methanolysis of the glyceride oils. Liquid‐liquid partitioning between acetonitrile and commerical pentane is suitable for purifying large quantities of methyl dimorphecolate. Methyl lesquerolate can be purified by distillation in vacuo as well as by liquid‐liquid partitioning. Chromatography and low‐temperature crystallization also were tried.