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Some recent developments in the homogeneous catalyzed hydrogenation of olefins
Author(s) -
Augustine Robert L.,
Van Peppen Jan F.
Publication year - 1970
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02639231
Subject(s) - isomerization , catalysis , homogeneous , olefin fiber , rhodium , chemistry , double bond , homogeneous catalysis , hydrogen , organic chemistry , photochemistry , thermodynamics , physics
It has been found that the amount of double bond isomerization accompanying homogeneous olefin hydrogenations over tris (triphenylphosphinechlororhodium is markedly influenced both by the duration of hydrogen presaturation of the catalyst and the presence of oxygen in the reaction mixture. These results are compared to those obtained over a heterogeneous catalyst, 5% rhodium on chareoal.