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Autoxidation products of 2,4‐decadienal
Author(s) -
Matthews R. F.,
Scanlan R. A.,
Libbey L. M.
Publication year - 1971
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02638534
Subject(s) - hexanal , chemistry , hexanoic acid , autoxidation , glyoxal , acetic acid , nonanal , organic chemistry , acrolein , benzaldehyde , chromatography , catalysis
2,4‐Decadienal was autoxidized by purging a purified sample with oxygen. An analysis of the autoxidative degradation products was made with tandem gas chromatography‐mass spectrometry. Additional information was obtained from the determination of the melting point of the dinitrophenylhydrazone derivatives and IR absorbency data. Pentane, furan, ethanal, hexanal, acrolein, butenal, 2‐heptenal, 2‐octenal, benzaldehyde, glyoxal, trans ‐2‐buten‐1,4‐dial, acetic acid, hexanoic acid, 2‐octenoic acid, 2,4‐decadienoic acid and benzene were identified.