7,10‐Dihydroxy‐8(E)‐Octadecenoic acid: Stereochemistry and a novel derivative, 7,10‐Dihydroxyoctadecanoic acid | Zendy

Knothe G. | Zendy; Bagby M. O. | Zendy; Peterson R. E. | Zendy; Hou C. T. | Zendy

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7,10‐Dihydroxy‐8(E)‐Octadecenoic acid: Stereochemistry and a novel derivative, 7,10‐Dihydroxyoctadecanoic acid

Author(s) -

Knothe G.,

Bagby M. O.,

Peterson R. E.,

Hou C. T.

Publication year - 1992

Publication title -

journal of the american oil chemists' society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.512

H-Index - 117

eISSN - 1558-9331

pISSN - 0003-021X

DOI - 10.1007/bf02636070

Subject(s) - oleic acid , derivative (finance) , bioconversion , circular dichroism , hydrate , chemistry , hydrazine (antidepressant) , absolute configuration , stereochemistry , chromatography , organic chemistry , biochemistry , financial economics , economics , fermentation

7,10‐Dihydroxy‐8(E)‐octadecenoic acid (obtained by bioconversion of oleic acid with the bacterial strain PR3) was hydrogenated with hydrazine hydrate under air in ethanolic solution to give a novel compound, 7,10‐dihydroxy‐octadecanoic acid. The absolute configuration of both compounds was determined with the aid of circular dichroism to be R,R. A different purification method for 7,10‐dihydroxy‐8(E)‐octadecenoic acid is described.

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