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Analysis of fat acid oxidation products by countercurrent distribution methods. V. Low‐temperature decomposition of methyl linoleate hydroperoxide
Author(s) -
Johnston A. E.,
Zilch K. T.,
Selke E.,
Dutton H. J.
Publication year - 1961
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02633582
Subject(s) - chemistry , peroxide , nitrogen , diene , oxygen , double bond , decomposition , conjugated diene , conjugated system , organic chemistry , copolymer , natural rubber , polymer
Methyl cis, trans diene conjugated linoleate hydroperoxide isolated by counterenrrent distritbution from 4ŶC, auatoxidation of methyl linoleate was stored in atmospheres of oxygen and of nitrogen at 4ŶC. in darkenss. Besides manometric changes, infrared and ultraviolet characteristics, peroxide value, diene conjugation, and molecular weights were followed on samples removed at various periods of storage up to 53 days. These same analyses were obtained on fractions obtained by counter‐current distributions. Evidence for the reaction that occurs on storage in oxygen may be summarized thus: 1 mole oxygen absorbed by linoleate hydroperoxides destroys 1 mole cis, trans diene conjugation, 1/2 mole peroxide group, and 1 mole linoleate hydroperoxide; dimers of varying polarities, scission acids, and isolated rans bonds are formed. Since to volume changes were observed in the nitrogen storage of methyl linoleate hydroperoxide, changes in chemical and physical characteristics can only be related to time of storage. Storage in nitrogen at 4ŶC, destroys diene conjugation, peroxides, and linoleate hydroperoxide and produces dimers of varying polaritics, seission neids, and isolated rans bonds. Destruction of diene conjugation was one‐fourth as rapid in a nitrogen atmosphere as in oxygen. While differences in reactions and products were observed between oxygen and nitrogen storage, particularly in rates and in countereurrent distribution patterns, the similarity of products from oxygen and nitrogen storage is remarkable. One methyl linoleate hydroperoxide is formed regardless of storage atmosphere, dimirization and attendant destruction of double bonds and peroxides proceed.