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Reactions of unsaturated fatty alcohols. X. Preparation of some copolymers of nonconjugated linseed vinyl ether
Author(s) -
De Jarlais W. J.,
Teeter H. M.
Publication year - 1960
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02631597
Subject(s) - copolymer , ether , linseed oil , vinyl ether , vinyl polymer , polymer chemistry , organic chemistry , materials science , chemistry , polymer
Summary Vinyl ethers were prepared from benzyl, 2‐phenylethyl, 3‐phenylpropyl, 2‐benzyloxyethyl, 2‐( para‐tertiary ‐butylphenoxy)‐ethyl, tetrahydrofurfuryl, and 2‐cyanoethyl alcohols. The vinyl ethers, as well as 1‐methoxy‐1,3‐butadiene and cyclohexyl vinyl ether, when copolymerized with nonconjugated linseed vinyl ether produced viscous liquids that baked to films of moderate hardness and with fair resistance to alkali and acid. These copolymer films offered little improvement in hardness over similarly prepared films from nonconjugated linseed vinyl ether homopolymer. Baked films of nonconjugated linseed‐2‐ ( para‐tertiary ‐butylphenoxy) ethyl vinyl ether copolymers had improved alkali resistance over the homopolymer baked films and were considered to be the best of the copolymer films studied.