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Polymerization of drying oils. III. Some observations on reaction of maleic anhydride with methyl oleate and methyl linoleate
Author(s) -
Teeter H. M.,
Geerts M. J.,
Cowan J. C.
Publication year - 1948
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02631517
Subject(s) - maleic anhydride , adduct , monomer , chemistry , methyl oleate , polyamide , polymer chemistry , polymerization , organic chemistry , copolymer , polymer , catalysis
Summary Adducts of maleic anhydride with methyl oleate, methyl linoleate, and monomeric distillate have been prepared. Reaction of the adducts with ethylene diamine gave a linear, soluble polyamide in the case of the oleate adduct, but gelation occurred at a low degree of reaction with other adducts. The linoleate adduct was separated into monomeric and polymeric components. It is suggested that this polymeric component is responsible for the rapid gelation of polyamides from the adducts of methyl linoleate and monomeric distillate.