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Kinetics of the reaction between chlorine and oleic acid in carbon tetrachloride solution
Author(s) -
Clegg G. T.,
Winter P.
Publication year - 1972
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02582528
Subject(s) - chlorine , carbon tetrachloride , hydrogen chloride , chemistry , oleic acid , kinetics , inorganic chemistry , order of reaction , chloride , chemical kinetics , carbon fibers , organic chemistry , reaction rate constant , materials science , biochemistry , physics , quantum mechanics , composite number , composite material
Kinetic data have been obtained for the reaction between chlorine and oleic acid in carbon tetrachloride solution by measuring the chlorine depletion and hydrogen chloride production as a function of residence time in a rod‐like flow system. The data are well correlated by a kinetic model incorporating parallel, second‐order addition and substitution reactions. Measured reaction rates are an order of magnitude less than those reported in a previous investigation which neglected substitution reactions.