Kinetics of the reaction between chlorine and oleic acid in carbon tetrachloride solution | Zendy

Clegg G. T. | Zendy; Winter P. | Zendy

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Kinetics of the reaction between chlorine and oleic acid in carbon tetrachloride solution

Author(s) -

Clegg G. T.,

Winter P.

Publication year - 1972

Publication title -

journal of the american oil chemists' society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.512

H-Index - 117

eISSN - 1558-9331

pISSN - 0003-021X

DOI - 10.1007/bf02582528

Subject(s) - chlorine , carbon tetrachloride , hydrogen chloride , chemistry , oleic acid , kinetics , inorganic chemistry , order of reaction , chloride , chemical kinetics , carbon fibers , organic chemistry , reaction rate constant , materials science , biochemistry , physics , quantum mechanics , composite number , composite material

Kinetic data have been obtained for the reaction between chlorine and oleic acid in carbon tetrachloride solution by measuring the chlorine depletion and hydrogen chloride production as a function of residence time in a rod‐like flow system. The data are well correlated by a kinetic model incorporating parallel, second‐order addition and substitution reactions. Measured reaction rates are an order of magnitude less than those reported in a previous investigation which neglected substitution reactions.

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