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Vinyl esters of some aldehydic acid acetals
Author(s) -
Pryde E. H.,
Moore D. J.,
Cowan J. C.
Publication year - 1965
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02558244
Subject(s) - chemistry , enol , peroxide , organic chemistry , ethylene glycol , polymerization , acetal , ethylene , polymer chemistry , catalysis , polymer
Vinylation of azelaaldehydic and brassylaldehydic acid cyclic acetals from ethylene glycol gave excellent yields of the vinyl esters. Under conditions of the vinyl exchange reaction used, acyclic acetals from monohydric alcohols cleaved to give enol‐ethers as major, inseparable impurities. Radical‐initiated polymerization of the pure vinyl esters of the aldehydic‐acid cyclic acetals resulted in crosslinking when initiation was by either peroxide or azobis (isobutyronitrile).