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Micro vapor‐phase hydrogenation monitored with tandem chromatography‐radioactivity. II. Evaluation of catalyst selectivity for linolenate
Author(s) -
Mounts T. L.,
Dutton H. J.
Publication year - 1967
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02558155
Subject(s) - selectivity , linolenate , catalysis , tandem , vapor phase , phase (matter) , chemistry , chromatography , high performance liquid chromatography , organic chemistry , combinatorial chemistry , inorganic chemistry , materials science , fatty acid , thermodynamics , physics , composite material
Micro vapor‐phase hydrogenation is a rapid and effective method of studying the kinetic characteristics of hydrogenation catalysts. Eight catalysts were investigated, and reaction rates and selectivity ratios determined by an analog computer. Fatty esters labeled with C 14 were utilized to clarify reactions and to assist in achieving a unique simulation of the data for a particular catalyst.