Non‐volatile a ‐branched chain fatty acid derivatives: IV. Addition of aryl esters to long chain olefins | Zendy

Bilyk A. | Zendy; Eisner A. | Zendy; Maerker G. | Zendy

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Non‐volatile a ‐branched chain fatty acid derivatives: IV. Addition of aryl esters to long chain olefins

Author(s) -

Bilyk A.,

Eisner A.,

Maerker G.

Publication year - 1969

Publication title -

journal of the american oil chemists' society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.512

H-Index - 117

eISSN - 1558-9331

pISSN - 0003-021X

DOI - 10.1007/bf02544369

Subject(s) - chemistry , phenylacetate , yield (engineering) , methyl oleate , peroxide , organic chemistry , long chain , aryl , fatty acid , medicinal chemistry , catalysis , biochemistry , alkyl , materials science , polymer science , metallurgy

The di‐tertiary butyl peroxide initiated free radical addition of methyl phenylacetate, methyl p ‐tolylacetate and methyl p ‐methoxyphenylacetate to 1‐decene gives two types of products. In addition to the expected a ‐branched esters, dehydrodimer (both meso and dl ) esters were also obtained. The highest yield of a ‐branched ester was obtained from methyl phenylacetate. Higher yields of the dehydrodimer esters were obtained from the substituted phenyl esters. Attempts to add methyl p ‐nitrophenylacetate to 1‐decene were not successful and no evidence for the formation of a dehydrodimer product was observed.

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