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Synthesis of sulfur heterocycles from α,β‐unsaturated carbonyl fatty acid esters
Author(s) -
Mustafa Jamal,
Ahmad M. S.,
Rauf A.,
Osman S. M.
Publication year - 1984
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02542172
Subject(s) - sulfur , allylic rearrangement , alkyl , chemistry , fatty acid , organic chemistry , catalysis
Alkyl chain substituted oxathiolanes from allylic oxo are described. Reaction of methyl 4‐oxo‐ trans ‐2‐hexadecenoate (1) with β‐mercaptoethanol yields methyl 4‐oxathiolane‐ trans ‐2‐hexadecenoate (II), methyl 4‐oxathiolane‐2(3)‐(S‐β‐mercaptoethyl acetate) hexadecanoate (III) and methyl 4‐oxathiolane‐2(3)‐(S‐β‐mercaptoethanol)hexadecanoate (IV).