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Chemical synthesis of H 3 ‐ and 1‐C 14 ‐labeled polyunsaturated fatty acids
Author(s) -
Stoffel W.
Publication year - 1965
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02541294
Subject(s) - polyunsaturated fatty acid , ozonolysis , chemistry , tritium , methylene , double bond , linolenic acid , fatty acid , unsaturated fatty acid , stereochemistry , organic chemistry , linoleic acid , physics , nuclear physics
Total syntheses of polyunsaturated fatty acids labeled at the double bonds or the terminal methylene groups with tritium and the carboxyl group with C 14 are discussed. The methods are applicable for all known unsaturated fatty acids with polyallylic structure and all‐cis configuration. Details for the synthesis of labeled े‐linolenic acid are given and methods of ozonolysis for determining the structure of unsaturated fatty acids are described.