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Secondary and tertiary amines derived from pelargonaldehyde and methyl azelaaldehydate
Author(s) -
Pryde E. H.,
Anders D. E.,
Cowan J. C.
Publication year - 1969
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02541210
Subject(s) - amine gas treating , raney nickel , tertiary amine , catalysis , chemistry , yield (engineering) , alkylation , nickel , organic chemistry , tris , ammonia , palladium , polymer chemistry , materials science , metallurgy , biochemistry
Reductive alkylation of ammonia with pelargonaldehyde or with methyl azelaaldehydate over Raney nickel catalyst produced dinonylamine or bis(8‐carbomethoxyoctyl)amine in good yields. Tertiary amine formation was minimized by the use of two immiscible solvents. When 10% palladium on charcoal was used in place of the nickel catalyst, trinonylamine and tris(8‐carbomethoxyoctyl)amine were formed in good yield in the absence of solvents.