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Decomposition of unsaturated fatty acid hydroperoxides by hemoglobin: Structures of major products of 13L‐hydroperoxy‐9,11‐octadecadienoic acid
Author(s) -
Hamberg Mats
Publication year - 1975
Publication title -
lipids
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.601
H-Index - 120
eISSN - 1558-9307
pISSN - 0024-4201
DOI - 10.1007/bf02532161
Subject(s) - decomposition , lipidology , clinical chemistry , chemistry , fatty acid , hemoglobin , organic chemistry , biochemistry
13L‐Hydroperoxy‐9,11‐octadecadienoic acid was decomposed rapidly in the presence of hemoglobin. The product consisted of five major compounds, i.e. 13‐keto‐9,11‐octadecadienoic acid, 13L‐hydroxy‐9,11‐octadecadienoic acid, erythro ‐11‐hydroxy‐12,13‐epoxy‐9‐octadecenoic acid, threo ‐11‐hydroxy‐12,13‐epoxy‐9‐octadecenoic acid, and 9DL‐hydroxy‐12,13‐epoxy‐10‐octadecenoic acid.