Autoxidation of polyunsaturated fatty esters on Silica | Zendy

Slawson Vida | Zendy; Adamson Arthur W. | Zendy; Mead James F. | Zendy

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Autoxidation of polyunsaturated fatty esters on Silica

Author(s) -

Slawson Vida,

Adamson Arthur W.,

Mead James F.

Publication year - 1973

Publication title -

lipids

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.601

H-Index - 120

eISSN - 1558-9307

pISSN - 0024-4201

DOI - 10.1007/bf02531809

Subject(s) - degree of unsaturation , autoxidation , polyunsaturated fatty acid , silicic acid , chemistry , silica gel , methyl oleate , organic chemistry , chromatography , adsorption , fatty acid , substrate (aquarium) , unsaturated fatty acid , catalysis , oceanography , geology

The stability of unsaturated methyl esters of fatty acid adsorbed on silica gel and silicic acid was studied by gas liquid chromatographic estimation of disappearance relative to a saturated internal standard. Variables included silica‐ester ratio, agitation, adsorbent particle size, and degree of unsaturation. Under the conditions of the experiment, destruction of substrate unsaturated ester at 80 C was more a function of time than of unsaturation or initial purity.

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