Synthesis and Characterization of Rhodium Complex Bearing Anionic CNC‐Type Pincer Ligand with Pyrrolide and Imidazo[1,5‐ a ]pyridin‐3‐ylidene Moieties | Zendy

Kuriyama Shogo | Zendy; Zhao Wenhao | Zendy; Nishibayashi Yoshiaki | Zendy

Premium

Synthesis and Characterization of Rhodium Complex Bearing Anionic CNC‐Type Pincer Ligand with Pyrrolide and Imidazo[1,5‐ a ]pyridin‐3‐ylidene Moieties

Author(s) -

Kuriyama Shogo,

Zhao Wenhao,

Nishibayashi Yoshiaki

Publication year - 2021

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.202100065

Subject(s) - pincer movement , rhodium , ligand (biochemistry) , pincer ligand , chemistry , lithium (medication) , nitro , electron paramagnetic resonance , medicinal chemistry , polymer chemistry , stereochemistry , combinatorial chemistry , organic chemistry , catalysis , receptor , biochemistry , medicine , alkyl , physics , nuclear magnetic resonance , endocrinology

A novel monoanionic CNC‐type pincer ligand featuring a pyrrolide as a central donor and imidazo[1,5‐ a ]pyridin‐3‐ylidenes as arm donors is designed and synthesized. The reaction of the lithium complex prepared from the pincer ligand with [RhCl(CO) 2 ] 2 gave the corresponding rhodium(I) carbonyl complex. X‐ray analysis and IR spectroscopy of the rhodium complex indicate that the newly designed and synthesized pincer ligand has an electron‐withdrawing character with a planar backbone.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research