Ionic Liquid Synthesis of (Et 3 S)[Ag 4 I 5 ] – A Structure Containing Basket‐Like Silver‐Iodide Cages with Ag 2  2+  Pairs | Zendy

Svensson Per H. | Zendy; Kloo Lars | Zendy

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Ionic Liquid Synthesis of (Et 3 S)[Ag 4 I 5 ] – A Structure Containing Basket‐Like Silver‐Iodide Cages with Ag 2 2+ Pairs

Author(s) -

Svensson Per H.,

Kloo Lars

Publication year - 2021

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.202000338

Subject(s) - iodide , ionic bonding , ionic liquid , molecule , band gap , compound semiconductor , crystallography , semiconductor , silver iodide , materials science , network structure , chemistry , stereochemistry , nanotechnology , ion , inorganic chemistry , optoelectronics , layer (electronics) , organic chemistry , computer science , epitaxy , silver halide , machine learning , catalysis

The compound (Et 3 S)[Ag 4 I 5 ], 1 , is readily synthesized from room‐temperature, ionic‐liquid media and displays a complex network structure of Ag 6 I 6 cages with Ag 2 2+ pairs forming 1D‐chains linked into layers distinctly separate from the disordered sulphonium cations. The compound should be regarded as a large‐bandgap semiconductor, but its significant structural voids qualify the compound a candidate for optoelectronic applications through the inclusion of suitable guest molecules.

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