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Sonochemical Synthesis, Crystal Structure and Antimicrobial Property of One‐dimensional Dinuclear Coordination Polymer
Author(s) -
Soltani Sajjad,
Akhbari Kamran,
White Jonathan
Publication year - 2021
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.202000268
Subject(s) - thermogravimetric analysis , hydrogen bond , coordination polymer , antibacterial activity , crystallography , crystal structure , chelation , zigzag , copper , materials science , polymer , chemistry , nuclear chemistry , inorganic chemistry , organic chemistry , molecule , bacteria , geometry , mathematics , biology , genetics
Dinuclear 1D coordination polymer of [NaCu 2 (pdc) 2 (H 2 O) 4 (OH)] n ( 1 ) (H 2 pdc = Pyridine‐2,6‐dicarboxylic acid) was synthesized by the solvothermal method, and its structure was investigated by single‐crystal X‐ray diffraction analysis. 1 has zigzag chains, which are converted to a 3D network through hydrogen bond interactions. Also, 1 was synthesized by sonochemical method ( 1‐Sono ). The structures of 1 and 1‐Sono were characterized by FT‐IR, XRD, FE‐SEM and thermogravimetric (TG) techniques. Antibacterial activity was evaluated by agar well diffusion method. Release of copper ions, chelation, and stability were the factors influencing antibacterial property. More effect of compounds against S. aureus strain was observed, and 1‐Sono exhibited better antibacterial activity than 1 .