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Thionylimido Complexes
Author(s) -
McGeachie Liam J. R.,
CarpenterWarren Cameron L.,
Cordes David B.,
Bühl Michael,
Gray Steven J.,
Hua Guoxiong,
Slawin Alexandra M. Z.,
Woollins J. Derek
Publication year - 2020
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.202000238
Subject(s) - antimony , copper , block (permutation group theory) , crystallography , chemistry , ligand (biochemistry) , metal , bond length , group (periodic table) , stereochemistry , inorganic chemistry , crystal structure , mathematics , geometry , organic chemistry , receptor , biochemistry
An improved route to d‐block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar 3 Sb(NSO) 2 ), and copper examples [CuBipy(PPh 3 )NSO]. The structures of eight complexes are reported. The observed variation in M–N–S bond angles is due to the combination of orbital overlap (ligand‐to‐metal bonding) and the degree of ionicity of the bonding.