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Highly Active Heterogeneous PdCl 2 /MOF Catalyst for Suzuki–Miyaura Cross‐Coupling Reactions of Aryl Chloride
Author(s) -
Gong XueFang,
Zhang LingYan,
Zhang HuiXin,
Cui YuMeng,
Jin FenChun,
Liu Yu,
Zhai YuFeng,
Li JinHeng,
Liu GuiYan,
Zeng YongFei
Publication year - 2020
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.202000132
Subject(s) - catalysis , aryl , chemistry , zirconium , substrate (aquarium) , selectivity , heterogeneous catalysis , chloride , coupling reaction , inorganic chemistry , chemical engineering , organic chemistry , alkyl , oceanography , engineering , geology
The exploration of highly efficient Pd/MOF heterogeneous catalyst system for the Suzuki–Miyaura cross‐coupling (SMC) reactions of aryl chlorides is still challenging. Herein, a PdCl 2 /UiO‐67‐bpydc was successfully synthesized by immobilizing a low amount of PdCl 2 onto the zirconium‐based MOF (UiO‐67‐bpydc). PdCl 2 /UiO‐67‐bpydc showed excellent catalytic performance and good recycle ability for the SMC reaction of aryl chlorides under an ambient condition. Furthermore, PdCl 2 /UiO‐67‐bpydc retains the high catalytic activity even after five cycles, and exhibited excellent substrate size selectivity.