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Fluorine in Small Molecules: Fluoromethyl Azide and Chalcogenocyanates
Author(s) -
Reichel Marco,
Egenhöfer Mara,
Krumm Burkhard,
Karaghiosoff Konstantin
Publication year - 2020
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.202000055
Subject(s) - azide , molecule , fluorine , potassium , chemistry , materials science , organic chemistry
Fluoromethylating agents are a highly studied and controversely discussed class of compounds. New fluoromethyl pseudohalides FCH 2 N 3 , FCH 2 SCN, and FCH 2 SeCN were prepared for the first time and their physical and spectroscopic properties investigated. Their synthesis is performed conveniently by fluoromethylation of the respective silver or potassium pseudohalogenides with fluoroiodomethane.