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Front Cover: Gallium and Indium Alkoxides with Hydride, Cyclopentadienediide and Copper(I) tert ‐Butoxide as further Components (Z. Anorg. Allg. Chem. 22/2019)
Author(s) -
Veith Michael,
Summa Daniela,
Annel Uwe,
Huch Volker
Publication year - 2019
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201970221
Subject(s) - alkoxide , indium , gallium , hydride , copper , chemistry , lewis acids and bases , metal , oxide , front cover , polymer chemistry , inorganic chemistry , cover (algebra) , organic chemistry , catalysis , engineering , mechanical engineering
The cover picture shows the structure of the hydrido galliumoxide‐alkoxide (H‐Ga) 5 (O‐iPr) 8 (O) emphasizing the inner Ga 5 O 9 polycyclic skeleton (R= iso ‐Propyl). Such Lewis‐acid/base agglomerates, based on metal alkoxides, can be used to combine not only hydride and oxide in a molecular compound, but also indium and C 5 H 4 2– as shown for In 4 (OtBu) 8 (C 5 H 4 ) 2 , or indium and copper as found in (py) 2 CuIn(OtBu) 4 or in [CuIn(OtBu) 4 ] 2 . Such molecules can be used as precursors for materials synthesis. More details can be found in the article by Michael Veith, Daniela Summa, Uwe Annel, and Volker Huch on page 1272.