Premium
A Ditopic Phosphane‐decorated Benzenedithiol as Scaffold for Di‐ and Trinuclear Complexes of Group‐10 Metals and Gold
Author(s) -
Schlindwein Simon H.,
Sibold Carlo,
Schenk Mareike,
Ringenberg Mark R.,
Feil Christoph M.,
Nieger Martin,
Gudat Dietrich
Publication year - 2020
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201900355
Subject(s) - ligand (biochemistry) , metal , chemistry , medicinal chemistry , chelation , benzene , nuclear chemistry , crystallography , stereochemistry , inorganic chemistry , organic chemistry , receptor , biochemistry
The ability of 3‐(diphenylphosphinomethyl)‐benzene‐1,2‐dithiol (pbdtH 2 ) to act as ditopic ligand was probed in reactions with selected group‐10‐metal complexes. Reactions with [(cod)PdCl 2 ] afforded a mixture of products identified as [Pd(pbdtH) 2 ], [Pd 2 (μ 2 ‐pbdt) 2 ] and [Pd 3 (μ 2 ‐pbdt) 2 Cl 2 ]. The polynuclear complexes could be isolated after suitably adjusting the reaction conditions, and heating of a mixture in a microwave reactor effected partial conversion into a further complex [Pd 3 (μ 2 ‐pbdt) 3 ]. Reaction of pbdtH 2 with [Ni(H 2 O) 6 Cl 2 ] gave rise to a complex [Ni 2 (μ 2 ‐pbdt) 2 ], which was shown to undergo two reversible 1e – ‐reduction steps. Reaction of [Pd(pbdtH) 2 ] with [Au(PPh 3 )Cl] afforded heterotrinuclear [PdAu 2 (μ 2 ‐pbdt) 2 (PPh 3 )]. All complexes were characterized by analytical, spectroscopic and single‐crystal X‐ray diffraction studies. Their molecular structures confirm the ability of the pbdt 2– unit to support simultaneous P,S‐ and S,S‐chelating coordination to two metal centers.