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Trialkylaluminum N‐Heterocyclic Olefin (NHO) Adducts as Catalysts for the Polymerization of Michael‐Type Monomers
Author(s) -
Watson Ian C.,
Zhou Yuqiao,
Ferguson Michael J.,
Kränzlein Moritz,
Rieger Bernhard,
Rivard Eric
Publication year - 2020
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201900331
Subject(s) - adduct , monomer , polymerization , olefin polymerization , catalysis , polymer chemistry , olefin fiber , chemistry , materials science , organic chemistry , polymer
The synthesis of new trialkylaluminum adducts with N‐heterocyclic olefin (NHO) ligands is described. These well‐defined complexes can catalyze the polymerization of various Michael‐type monomers, such as 2‐vinylpyridine, methylacrylate, and dimethylacrylamide.