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Synthesis of “Clickable” Nano Metal‐organic Framework by Generic Postsynthetic Modification Route
Author(s) -
Yue Dan,
Chen Dong,
Zhang Xin,
Huang Yike,
Wang Zhenling
Publication year - 2019
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201900225
Subject(s) - click chemistry , azide , nanotechnology , nano , metal organic framework , materials science , surface modification , nanocrystal , combinatorial chemistry , chemistry , organic chemistry , composite material , adsorption
Organic azides have been somewhat popularized due to their pivotal role in the emerging field of “click chemistry”. A simple approach has been used for the synthesis of uniform nano Fe‐MIL‐88B‐NH 2 , and a generic postsynthetic modification route has been developed for the synthesis of azide‐modified nano Fe‐MIL‐88B‐N 3 . The approach also has been used to synthesize the azide‐modified IRMOF‐3(‐N 3 ). These new azide‐modified Fe‐MIL‐88B‐N 3 nanocrystals hold promising potential for the applications in the fields of “click chemistry”, nanotechnology devices and nano composite membranes.