Synthesis and Characterisation of the Nitridocuprate(I) Nitride Carbodiimide (Sr 6 N)[CuN 2 ][CN 2 ] 2 | Zendy

Clark William P. | Zendy; Niewa Rainer | Zendy

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Synthesis and Characterisation of the Nitridocuprate(I) Nitride Carbodiimide (Sr 6 N)[CuN 2 ][CN 2 ] 2

Author(s) -

Clark William P.,

Niewa Rainer

Publication year - 2020

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201900222

Subject(s) - nitride , raman spectroscopy , carbodiimide , strontium , crystallography , ampoule , alkali metal , materials science , single crystal , metal , alkaline earth metal , analytical chemistry (journal) , inorganic chemistry , chemistry , nanotechnology , metallurgy , polymer chemistry , composite material , organic chemistry , physics , layer (electronics) , optics

The strontium nitridocuprate(I) nitride carbodiimide has been successfully produced and characterised. Single crystals were grown in metal ampoules, utilising an alkali metal as a fluxing agent. Structural characterisation was conducted via single‐crystal X‐ray diffraction and the identity of the [CN 2 ] 2– anion as carbodiimide was confirmed by Raman spectroscopy. Diamagnetic behaviour over a large temperature range supports the copper(I) electronic state.

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