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Synthesis and Structures of Dinuclear Aluminum Complexes Based on Bis(β‐diketiminate) Ligands
Author(s) -
Desat Marcella E.,
Kretschmer Robert
Publication year - 2020
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201900193
Subject(s) - elemental analysis , aluminium , alkyl , chemistry , single crystal , infrared spectroscopy , crystallography , stereochemistry , nuclear magnetic resonance spectroscopy , polymer chemistry , inorganic chemistry , organic chemistry
A series of ten dinuclear aluminum alkyl complexes based on rigid, semirigid, and flexible bis(β‐diketiminate) ligands (NacNac) has been obtained from the reaction of trimethylaluminum and the corresponding bis(β‐diketimine)s. All compounds were fully characterized using NMR and IR spectroscopy and elemental analysis. The molecular structures of five compounds have been investigated by means of single‐crystal X‐ray diffraction analysis.