Antimony(V) Bromide and Polybromide Complexes with N‐alkylated Quinolinium or Isoquinolinium Cations: Substituent‐dependent Assembly of Polymeric Frameworks | Zendy

Adonin Sergey A. | Zendy; Bondarenko Mikhail A. | Zendy; Novikov Alexander S. | Zendy; Abramov Pavel A. | Zendy; Plyusnin Pavel E. | Zendy; Sokolov Maxim N. | Zendy; Fedin Vladimir P. | Zendy

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Antimony(V) Bromide and Polybromide Complexes with N‐alkylated Quinolinium or Isoquinolinium Cations: Substituent‐dependent Assembly of Polymeric Frameworks

Author(s) -

Adonin Sergey A.,

Bondarenko Mikhail A.,

Novikov Alexander S.,

Abramov Pavel A.,

Plyusnin Pavel E.,

Sokolov Maxim N.,

Fedin Vladimir P.

Publication year - 2019

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201900165

Subject(s) - chemistry , substituent , bromide , antimony , alkylation , adduct , medicinal chemistry , thermal stability , supramolecular chemistry , inorganic chemistry , crystal structure , organic chemistry , catalysis

Reactions of [Sb III Br 6 ] 3– with Br 2 in HBr in the presence of N‐substituted quinolinium or isoquinolinium cations result in new complexes of hexabromidoantimonates of Sb V and their polybromide adducts: (N‐MeQuin) 2 {[SbBr 6 ](Br 3 )} ( 1 ), (N‐MeIsoquin) 2 {[SbBr 6 ](Br 3 )} ( 2 ), and (N‐EtQuin)[SbBr 6 ] ( 3 ). Thermal stability was studied; estimated energies of supramolecular Br ··· Br interactions were calculated.

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