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Synthesis of Nitro‐Octaaza Derivatives of Reduced Anthracene
Author(s) -
Il'yasov Sergey G.,
Glukhacheva Vera S.,
Yermoshina Valentina A.,
Eltsov Ilia V.
Publication year - 2019
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.201900091
Subject(s) - nitric acid , chemistry , nitrous acid , anthracene , sulfuric acid , acetic anhydride , nitro , thermal decomposition , hydrolysis , decomposition , thermal stability , organic chemistry , acetic acid , tetrazine , nitration , medicinal chemistry , nuclear chemistry , catalysis , alkyl
Nitro compounds of octaaza derivatives of reduced anthracene were synthesized for the first time by reaction of 2,3,4a,6,7,8a,9,10‐octaaza‐4,8‐dioxo‐3,4,4a,7,8,8a,9,9a,10,10a‐decahydroanthracene with nitric acid, mixed nitric acid/sulfuric acid, and nitric acid/acetic anhydride at between –20 and –30 °C. In addition, 1,2,4,5‐tetrazine azido derivatives were obtained by hydrolytic decomposition of the starting compound by nitrous acid. All the resultant compounds exhibit high thermal stability.